Long-range spin-spin interactions in the C-13-n.m.r. spectra of the nickel(II) complex of the Schiff base of (S)-N-benzylproline (2-benzoylphenyl)amide and glycine. Quantum-chemical calculations and possible donation of electron density...

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12640%2F03%3A00004772" target="_blank" >RIV/60076658:12640/03:00004772 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Long-range spin-spin interactions in the C-13-n.m.r. spectra of the nickel(II) complex of the Schiff base of (S)-N-benzylproline (2-benzoylphenyl)amide and glycine. Quantum-chemical calculations and possible donation of electron density...

Original language description

Long-range [(n)J(C-13, C-13), (n)J(N-15, N-15) and (n)J(N-15, C-13)] interactions in the C-13-n.m.r. spectra of CDCl3 solutions of selectively labeled nickel(II) complexes of the Schiff base derived from (S)-N-benzylproline (2-benzoylphenyl)amide and glycine provide experimental evidence for the necessity of the donation of electron density from the pi-system of the benzyl ring to the nickel orbitals. No such interactions were observed in (H-2) DMSO solutions, where the complex exists in a different conformation.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BO - Biophysics

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Transition Metal Chemistry

ISSN

0340-4285

e-ISSN

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Volume of the periodical

28

Issue of the periodical within the volume

4

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

475-481

UT code for WoS article

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EID of the result in the Scopus database

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