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Synthesis and absolute configuration of hyperaspine, an alkaloid of the ladybird Hyperaspis campestris

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60077395%3A_____%2F05%3A00020884" target="_blank" >RIV/60077395:_____/05:00020884 - isvavai.cz</a>

  • Alternative codes found

    RIV/60076658:12310/05:00008694

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and absolute configuration of hyperaspine, an alkaloid of the ladybird Hyperaspis campestris

  • Original language description

    Hyperaspine, isolated from the European ladybird Hyperaspis campestris (Coccinellidae), is the first representative of a new type of ladybird alkaloids having a 3-oxaquinolizidine skeleton. A new total synthesi sof hyperaspine starting from piperidin-4-one has been achieved. The absolute configuration of the natural alkaloid was unequivocally established by HPLC analyse on a chiral column.

  • Czech name

    Syntéza a konfigurace hyperaspinu, alkaloidu slunéčka Hyperaspis campestris

  • Czech description

    Hyperaspin izolovaný z evropského slunéčka Hyperaspis campestris (Coccinellidae), je první slunéččí obranný alkaloid nového typu obsahující kostru 3-oxachinolizidinu. Bylo dosaženo úplné umělé syntézy hyperaspinu vycházející z piperidin-4-onu. Stereokonfigurace přírodního alkaloidu byla jasně zjištěna analýzou HPLC na chorální koloně.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CE - Biochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    European Journal of Organic Chemistry

  • ISSN

    1434-193X

  • e-ISSN

  • Volume of the periodical

    7

  • Issue of the periodical within the volume

    -

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    1378-1383

  • UT code for WoS article

  • EID of the result in the Scopus database