Duplex treatment of plasma nitriding and manganese phosphating of 42CrMo4 steel for corrosion resistance increasing
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60162694%3AG43__%2F17%3A00534613" target="_blank" >RIV/60162694:G43__/17:00534613 - isvavai.cz</a>
Alternative codes found
RIV/00216305:26220/17:PU136113
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Duplex treatment of plasma nitriding and manganese phosphating of 42CrMo4 steel for corrosion resistance increasing
Original language description
Plasma nitriding is widely used as a final operation to improve wear, fatigue and corrosion resistance of industrial parts. Nevertheless, corrosion resistance can be further increased by post-oxidizing or by manganese phosphate conversion coating. This paper considers the duplex treatment of plasma nitriding and manganese phosphating of 42CrMo4 steel surface, widely used for manufacturing of breech mechanism in the armament production. Plasma nitriding was carried out at 500 °C for 15 h in different nitriding atmosphere having hydrogen and nitrogen gas flow ratio with 3 to 1 (l/h) and of 1 to 3 (l/h). Plasma nitrided steel samples were manganese phosphated (without lubrication). The treated samples were characterized using metallographic techniques, microhardness, and NSS corrosion tests. Different compound layer thickness under different nitriding gas ratio was confirmed. The X-ray diffraction analysis (XRD) confirmed different volumes of ε-Fe2-3N, γ'-Fe4N nitrides in the compound layers and hureaulite Mn5 (PO3 (OH))2 (PO4)2 (H2O)4 in the manganese phosphate coatings. The visual and gravimetric evaluation was carried out and corrosion rates modified to weight gains were calculated for corrosion evaluation. After removing of corrosion products weight losses were measured and pitting factors were calculated. Duplex treatment (manganese phosphating after plasma nitriding) also displayed increased corrosion resistance and suppressed pitting propagation in comparison with the plasma nitrided steel samples and a potential to further increase of corrosion resistance of plasma nitrided structural steels.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
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OECD FORD branch
20501 - Materials engineering
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
METAL 2017 - 26TH ANNIVERSARY INTERNATIONAL CONFERENCE ON METALLURGY AND MATERIALS
ISBN
978-808729479-6
ISSN
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e-ISSN
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Number of pages
7
Pages from-to
1077-1084
Publisher name
TANGER Ltd
Place of publication
Brno, Czech Republic
Event location
Brno
Event date
May 24, 2017
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000434346900172