Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60162694%3AG44__%2F09%3A00002168" target="_blank" >RIV/60162694:G44__/09:00002168 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles
Original language description
The reactions of p-nitrophenyl acetate (PNPA) and p-nitrophenyl benzoate (PNPB) with _-nucleophile oximates i.e., 2, 3-butane dione monoximate, pralidoximate;and other oximates has been studied in the presence of different cationic surfactants. The firstorder rate constant increases with increasing surfactant concentration. The extent of acceleration is dependent of head group of surfactants. The reaction of PNPA with oximes gains greater rate enhancements than the corresponding reaction of PNPB in thepresence of cationic surfactants.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
FP - Other medical fields
OECD FORD branch
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Project
<a href="/en/project/OPUOFVZ200603" target="_blank" >OPUOFVZ200603: A new method of prophylaxis, decontamination, diagnostics and therapy afer intoxication with nerve agents and yperits</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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