Oxidation reactions of carbaryl in aqueous solutions

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60460709%3A41210%2F22%3A91286" target="_blank" >RIV/60460709:41210/22:91286 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0301010421003384" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0301010421003384</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.chemphys.2021.111427" target="_blank" >10.1016/j.chemphys.2021.111427</a>

Result language
angličtina
Original language name
Oxidation reactions of carbaryl in aqueous solutions
Original language description
Hydroxyl radical induced oxidation of carbaryl has been studied using steady state photolysis followed by highresolution mass spectrometry, pulse radiolysis, and theoretical calculations. Naphthoquinones are found to undergo ring opening and the corresponding products are identified. The reaction of SO4- with carbaryl, on the other hand, results the radical cation of parent molecule which exhibits reasonable stability in the pulse radiolysis timescale. Total organic carbon analysis after H2O2 UV photolysis revealed that nearly 70% of the organic content is mineralized after 35 min of irradiation, which demonstrates the potential application of oxidative methods towards the degradation of carbaryl.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
40104 - Soil science

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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