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Complexation of some protonated alpha-amino acid methyl esters with benzo-18-crown-6 in nitrobenzene saturated with water

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60460709%3A41330%2F13%3A60910" target="_blank" >RIV/60460709:41330/13:60910 - isvavai.cz</a>

  • Alternative codes found

    RIV/46356088:_____/13:#0001429

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Complexation of some protonated alpha-amino acid methyl esters with benzo-18-crown-6 in nitrobenzene saturated with water

  • Original language description

    From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) +1 center dot Na+(nb)double left right arrow 1 center dot C+ (nb)+Na+ (aq) taking place in the two-phase water-nitrobenzene system (C+ = protonated alpha-amino acid methyl ester, 1=benzo-18-crown-6; aq=aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1 center dot C+ complex species in nitrobenzene saturated withwater were calculated; they were found to increase in the following cation order: protonated L-tryptophan methyl ester<protonated L-phenylalanine methyl ester<protonated L-leucine methyl ester, protonated L-methionine methyl ester<protonated L-valine methyl ester. (C) 2013 Elsevier B.V. All rights reserved.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    JOURNAL OF MOLECULAR LIQUIDS

  • ISSN

    0167-7322

  • e-ISSN

  • Volume of the periodical

    2013

  • Issue of the periodical within the volume

    180

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    4

  • Pages from-to

    221-224

  • UT code for WoS article

    000316509300035

  • EID of the result in the Scopus database