Iron Aminocarbene Complexes Containing a Double C=C Bond in the N-Substituent: Preparation and Reactivity

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F01%3A00004883" target="_blank" >RIV/60461373:22310/01:00004883 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22330/01:00004883

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Iron Aminocarbene Complexes Containing a Double C=C Bond in the N-Substituent: Preparation and Reactivity

Original language description

Reaction of N,N-diallylbenzamide with Na2Fe(CO)4 and Me3SiCl afforded chelated cis-tricarbonyl[(2-N-allyl-N-allylamino)(phenyl)carbene]iron(0) directly. The same reaction of -(3-buten-1-yl)-N-methylbenzamide proceeded with migration of the double bond tothe allylic position, giving a mixture of chelated cis-tricarbonyl[(2-N-(2-butenyl)-N-methylamino)(phenyl)carbene]iron(0) and nonchelated tetracarbonyl[(N-(2-butenyl)-N-methylamino)(phenyl)carbene]iron(0). N-(3-Buten-2,2-dimethyl-1-yl)-N-methylbenzamide, in which migration of double bond is not possible, gave a mixture of E and Z isomers of nonchelated tetracarbonyl[(N-(2,2-dimethyl-3-butenyl)-N-methylamino)(phenyl)carbene]iron(0). Thermolysis of the latter furnished 1-methyl-3,3-dimethyl-

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

25

Country of publishing house

US - UNITED STATES

Number of pages

6

Pages from-to

5419-5424

UT code for WoS article

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EID of the result in the Scopus database

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