Synthesis of polyfluoroalkylated cyclopentenes as model compounds for fluorophilic cyclopentadienes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F02%3A00006492" target="_blank" >RIV/60461373:22310/02:00006492 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis of polyfluoroalkylated cyclopentenes as model compounds for fluorophilic cyclopentadienes

Original language description

Nucleophilic opening of 6-oxabicyclo[3.1.0]hexane (1) epoxide ring by ethenylmagnesium bromide was employed for the preparation of 2-ethenylcyclopentan-1-ol (2). Radical addition of perfluoroalkyl iodides 3 to alkenol 2 afforded (polyfluoroiodoalkyl)cyclopentanols 4, which were deiodinated with tributylstannane to (polyfluoroalkyl)cyclopentanols 5, followed by dehydration with Nafion-H to the target (polyfluoroalkyl)cyclopentenes 6, which are potential intermediates for fluorous chemistry.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Collection of Czechoslovak Chemical Communications

ISSN

0010-0765

e-ISSN

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Volume of the periodical

67

Issue of the periodical within the volume

9

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

14

Pages from-to

1345-1358

UT code for WoS article

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EID of the result in the Scopus database

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