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Synthesis of polyfluoroalkylated cyclopentenes as model compounds for fluorophilic cyclopentadienes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F02%3A00006492" target="_blank" >RIV/60461373:22310/02:00006492 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis of polyfluoroalkylated cyclopentenes as model compounds for fluorophilic cyclopentadienes

  • Original language description

    Nucleophilic opening of 6-oxabicyclo[3.1.0]hexane (1) epoxide ring by ethenylmagnesium bromide was employed for the preparation of 2-ethenylcyclopentan-1-ol (2). Radical addition of perfluoroalkyl iodides 3 to alkenol 2 afforded (polyfluoroiodoalkyl)cyclopentanols 4, which were deiodinated with tributylstannane to (polyfluoroalkyl)cyclopentanols 5, followed by dehydration with Nafion-H to the target (polyfluoroalkyl)cyclopentenes 6, which are potential intermediates for fluorous chemistry.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    67

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    14

  • Pages from-to

    1345-1358

  • UT code for WoS article

  • EID of the result in the Scopus database