Light-driven catalysts based on flavin-zinc(II)-cyclen system

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F03%3A00007917" target="_blank" >RIV/60461373:22310/03:00007917 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

Light-driven catalysts based on flavin-zinc(II)-cyclen system

Original language description

It was found that the flavin-zinc(II)-cyclen derivative 1a catalyzed efficiently photoinduced electron-transfer oxidation of 4-methoxybenzyl alcohol in acetonitril under atmospheric pressure of oxygen. After reduction by sodium dithionite and after irradiation, reduced molecule 1b cleaved thymine dimer. In these reactions, presence of the covalently bound zinc(II)-cyclen subunit is crucial for efficient functioning of our photocatalysts. Photooxidations by water soluble derivative 1 were also tested inaqueous solutions.

Czech name

—

Czech description

—

Type

D - Article in proceedings

CEP classification

CC - Organic chemistry

OECD FORD branch

—

Project

—

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

Intra and Intermolecular Transfer

ISBN

—

ISSN

—

e-ISSN

—

Number of pages

1

Pages from-to

29-29

Publisher name

Universität Köln

Place of publication

Köln

Event location

Walberberg, Germany

Event date

Oct 29, 2003

Type of event by nationality

WRD - Celosvětová akce

UT code for WoS article

—