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Comparative kinetic study of atrazine photodegradation in aqueous Fe(ClO4)3 solutions and TiO2 suspensions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F03%3A00008107" target="_blank" >RIV/60461373:22310/03:00008107 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/03:54030065

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Comparative kinetic study of atrazine photodegradation in aqueous Fe(ClO4)3 solutions and TiO2 suspensions

  • Original language description

    Kinetics of oxidative photodegradation of atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) in both homogenous solutions of Fe(ClO4)3 and heterogeneous suspensions of TiO2 were investigated and compared. Comparing freshly prepared solutions of Fe(ClO4)3 with aqueous slurry of TiO2 P25 (Degussa), the photodegradation rates were similar. Colloidal suspensions of quantum sized particles Q-TiO2 were less photoactive than the P25 slurry. Doping of the quantum-sized particles by Fe3+ caused a red shift of the semiconductor absorption but influenced the photocatalytic activity negatively. Comparing to Q-TiO2, the degradation rate for Q-TiO2 (1% Fe3+) decreased while for the corresponding mixture of Q-TiO2 and 1% Fe(ClO4)3 it increased.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Appl.Catalysis B:Environ

  • ISSN

    0926-3373

  • e-ISSN

  • Volume of the periodical

    40

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    BE - BELGIUM

  • Number of pages

    12

  • Pages from-to

    1-12

  • UT code for WoS article

  • EID of the result in the Scopus database