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Influence of the degree of sulphonation on transport properties of poly(2,6-dimethyl-1,4-phenylenoxide) membranes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F03%3A00008185" target="_blank" >RIV/60461373:22310/03:00008185 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Influence of the degree of sulphonation on transport properties of poly(2,6-dimethyl-1,4-phenylenoxide) membranes

  • Original language description

    Proton exchange membranes suitable for aplication in fuel cells have been prepared from a variety of polymeric materials. The typical representatives of these membranes are perfluorosulphonate polymers, such as Nafion. Regardless of its high proton conductivity, mechanical and chemical stability, Nafion also has serious disadvantages. Besides high production costs is its relatively high permeability to methanol. In this study was prepared the new type of ion?exchange membrane based on the sulphonated poly(2,6?dimethyl?1,4- -phenyleneoxide) (SPPO). This polymer is an attractive material for the preparation of membranes because it possesses excellent film- and membrane-forming properties as well as high thermal and chemical stability. Aim of this study was to determine influence of degree of sulphonation of SPPO in the range 10 to 55 % on its charge and mass transfer properties. Ion conductivity, ion exchange capacity and swelling in water vapour were followed for the individual membrane

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    GDCh - Jahrestagung Chemie 2003

  • ISBN

    3-936028-10-9

  • ISSN

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

    49

  • Publisher name

    Media Process Management GmbH

  • Place of publication

    Mainz

  • Event location

    Munchen

  • Event date

    Oct 16, 2003

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article