Reductive Heck reaction of 6-halopurines

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F04%3A00012349" target="_blank" >RIV/60461373:22310/04:00012349 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Reductive Heck reaction of 6-halopurines
Original language description
Alkenylation of 9-benzyl-6-halopurines with alkenes does not proceed under conventional Heck conditions. However, in the presence of triethylammonium formate a mixture of the corresponding saturated products was obtained. In contrast to the classical Heck reaction, the regioselectivity of this process is low giving a mixture of both a- and b-products regardless of the electronic nature of the substituent on the double bond of the alkene.
Czech name
"Reductive Heck reaction of 6-halopurines
Czech description
Alkenylation of 9-benzyl-6-halopurines with alkenes does not proceed under conventional Heck conditions. However, in the presence of triethylammonium formate a mixture of the corresponding saturated products was obtained. In contrast to the classical Heck reaction, the regioselectivity of this process is low giving a mixture of both a- and b-products regardless of the electronic nature of the substituent on the double bond of the alkene.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F03%2F0035" target="_blank" >GA203/03/0035: Synthesis of novel purine derivatives bearing functionalized C-substituents in the position 6</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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