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Thermodynamic prediction of composition of calcia-stabilised zirconia plasma-sprayed coatings

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F05%3A00014071" target="_blank" >RIV/60461373:22310/05:00014071 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermodynamic prediction of composition of calcia-stabilised zirconia plasma-sprayed coatings

  • Original language description

    Plasma-sprayed zirconia-based coatings are of great interest due to their excellent mechanical and thermal properties. This contribution is focused on thermodynamic aspects of the plasma-spraying of calcia-stabilized zirconia. The thermodynamic analysisof the system Zr-Ca-O-N was performed. The Gibbs energy minimization method was used for calculations of equilibrium composition of this system in the temperature range of 1000 - 4000 K. The gaseous phase consists of 11 species (Ca, Ca2, CaO, Zr, ZrO, ZrO2, ZrN, O, O2, N and N2), the oxide melt CaO-ZrO2, cubic and tetragonal solid solutions CaO-ZrO2 and pure solid substances ZrO2(monoclinic), CaO, CaZrO3, Ca6Zr19O44 and ZrN were included into the calculations. Calculated results reveal that the calcium-containing gaseous species are more stable than those of zirconium and the ratio of Ca/Zr in condensed phases (solid or liquid) is less than this ratio in input feedstock powder. So CaZrO3 and cubic solid solution CaO-ZrO2 represent the e

  • Czech name

    Termodynamická predikce složení plasmově stříkaných povlaků ZrO2-CaO

  • Czech description

    Termodynamická predikce složení plasmově stříkaných povlaků ZrO2-CaO

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    JG - Metallurgy, metal materials

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA106%2F03%2F0710" target="_blank" >GA106/03/0710: Composition changes of ceramic and metallic materials during their plasma spraying</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů