Single crystal growth of Bi1-xSrxMnO3 - Thermodynamics and experiment
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F06%3A00017502" target="_blank" >RIV/60461373:22310/06:00017502 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/06:00017008
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Single crystal growth of Bi1-xSrxMnO3 - Thermodynamics and experiment
Original language description
The primary crystallization field of a perovskite solid solution Bi1−xSrxMnO3−δ was delimited by calculating the respective phase equilibria in the quaternary Bi-Sr-Mn-O system. The calculations are based on the recent assessment involving all three ternary subsystems, a quaternary liquid approximated as a mixture of Mn, MnO, Mn2O3, SrO and Bi2O3 species with binary Redlich-Kister coefficients and the perovskite phase described in terms of a point defect model allowing Sr2+ for Bi3+ substitution, oxygen vacancy formation and the related Mn3+/Mn4+ mixing on Mn-sublattice. The crystallization path and the composition of the crystallized solid solution are compared with single crystal growth experiments performed by self-flux method froma Bi-rich melt. The crystallization path obtained for a selected feed composition for which the largest and high quality single crystal have been grown, turns out to end very close to the global eutectic point.
Czech name
Příprava monokrystalů Bi1-xSrxMnO3 - Termodynamický model a experiment
Czech description
Příprava monokrystalů Bi1-xSrxMnO3 - Termodynamický model a experiment
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BJ - Thermodynamics
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F03%2F0924" target="_blank" >GA203/03/0924: Ordering phenomena and chemical bond in bismuth based manganites</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Thermochimica Acta
ISSN
0040-6031
e-ISSN
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Volume of the periodical
450
Issue of the periodical within the volume
1-2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
4
Pages from-to
38-41
UT code for WoS article
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EID of the result in the Scopus database
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