Cyclic ketones oxidation by hydrogen peroxide

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F09%3A00021462" target="_blank" >RIV/60461373:22310/09:00021462 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Cyclic ketones oxidation by hydrogen peroxide
Original language description
Introduction Oxidation of ketones, cyclic ketones or aldehydes to esters, lactones or hydroxyderivatives is known reaction also called as Baeyer-Villiger oxidation. This reaction on carbonyl group take place due to the influence of strong oxidizing agents as peroxoacetic acid, m-chloroperbenzoic acids and others. Using these agents the waste compounds are formed during Baeyer-Villiger oxidation that is necessary to isolate from reaction mixture and ecologically eliminate. Using hydrogen peroxide as an oxidation agent in Baeyer-Villiger oxidation is convenient from ecological point of view. The only waste compound is water. Unfortunately this agent is not very active and the co-use of catalyst is necessary. As a catalyst for this type of reaction beta zeolites or Sn modified MCM-41 are used. Results and Discussion Using hydrogen peroxide as oxidation agent has some disadvantages ? water, formed during reaction, can hydrolyze demanded product (ester or lactone) and lower the activity of
Czech name
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Czech description
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Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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