Organometallic Catalyst Immobilization and its Use for Selective Hydrogenations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F10%3A00022941" target="_blank" >RIV/60461373:22310/10:00022941 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Organometallic Catalyst Immobilization and its Use for Selective Hydrogenations
Original language description
The main disadvantage of organometallic catalysts used in selective hydrogenations (e.g. low thermal stability, limited reuse possibility) can be eliminated by their immobilization on solid materials. Furthermore, it was observed preserving or even improving their properties (especially high selectivity) after their immobilization. Four types of organometallic substances immobilizations are available ? the immobilization via hydrogen bonds, the immobilization by ionic exchange, the immobilization by a covalent bond formation, and the physical immobilization, so called ?ship in a bottle?. Silica materials enriched on silanol groups are often used as the supports for the immobilization by hydrogen bonds, providing the metal complexes containing a ligandcapable hydrogen bonds formation. The immobilization by ionic exchange can be achieved on ionic and anionic clays for charged complexes. Silica materials are usually used as the supports for the immobilization by a covalent bond. It requi
Czech name
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Czech description
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Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Book/collection name
Organometallic Compounds: Preparation, Structure and Properties
ISBN
978-1-60741-917-4
Number of pages of the result
23
Pages from-to
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Number of pages of the book
519
Publisher name
Nova Science Publishers,Hauppauge
Place of publication
New York
UT code for WoS chapter
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