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Nitrile hydrogenation on solid catalysts - new insights into reaction mechanism

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F12%3A43894476" target="_blank" >RIV/60461373:22310/12:43894476 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11144-012-0497-2" target="_blank" >http://dx.doi.org/10.1007/s11144-012-0497-2</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11144-012-0497-2" target="_blank" >10.1007/s11144-012-0497-2</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Nitrile hydrogenation on solid catalysts - new insights into reaction mechanism

  • Original language description

    The various speculative mechanisms proposed for heterogeneous nitrile hydrogenation are discussed. It seems very likely from current knowledge that aminocarbene complexes and aldimines, coordinated to a metal via the pí-system of a C=N double bond and/orvia the nitrogen lone pair, will prevail among the surface intermediates suggested for nitrile hydrogenation on palladium or platinum, whereas hydrogenation on a cobalt or nickel surface will likely be associated with the formation of nitrene intermediates. This duality provides a satisfactory explanation for the selectivity differences between metal catalysts in nitrile hydrogenation to primary amines.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Current Organic Chemistry

  • ISSN

    1385-2728

  • e-ISSN

  • Volume of the periodical

    16

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    16

  • Pages from-to

    988-1004

  • UT code for WoS article

    000302778400004

  • EID of the result in the Scopus database