Immobilization of pyridinium nitrate and its application for the catalytic converting of ?-pinene oxide

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43894065" target="_blank" >RIV/60461373:22310/13:43894065 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Immobilization of pyridinium nitrate and its application for the catalytic converting of ?-pinene oxide
Original language description
In this paper, differences among the catalytic effects of individual ammonium nitrates and influences of the catalysts used either in homogeneous and, moreover, pyridinium nitrate in heterogeneous forms of the catalytic converting of ?-pinene oxide to perillic alcohol were studied. A special attention was paid to the heterogeneously catalyzed reaction where the representative of the used catalysts, pyridinium nitrate, was immobilized on various supports?mesoporous molecular sieves (MCM-41, SBA-15), silica and smectites (hectorite, montmorillonite K-10 and bentonite). Based on the obtained results, the individual influences on the course of the catalytic splitting, namely the properties and modifications of supporting materials were discussed. The bestresults using the catalyst immobilized on hectorite were achieved. The maximum relative concentration was 64 % for perillic alcohol and 17 % for perillic alcohol isomers 17 %.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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