Ionic Liquids as Potential Supporting Electrolytes for the Anodic Oxidation of 4-methylanisole.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895454" target="_blank" >RIV/60461373:22310/13:43895454 - isvavai.cz</a>
Result on the web
<a href="http://jes.ecsdl.org/content/160/8/G117" target="_blank" >http://jes.ecsdl.org/content/160/8/G117</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1149/2.041308jes" target="_blank" >10.1149/2.041308jes</a>
Alternative languages
Result language
angličtina
Original language name
Ionic Liquids as Potential Supporting Electrolytes for the Anodic Oxidation of 4-methylanisole.
Original language description
The subject of this article is the mechanism and kinetics of 4-methylanisole methoxylation in two ionic liquid (IL) environments, namely triethylsulfonium bis(trifluoromethylsulfonyl)imide and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, dissolved in methanol. The investigations focused on the electrochemical behavior of 4-methylanisole, 4-methoxy-benzyl-methyl-ether and 4-methoxybenzaldehyde dimethyl acetal as the substrate and intermediates of the reaction studied. Voltammetry on aglassy carbon stationary electrode and a rotating disk electrode was used to accomplish this task. The results showed that both ILs behave as an indifferent supporting electrolyte in methanol solutions. The methoxylation kinetics of the individual compounds was described in terms of Tafel kinetics. A generalized form of the Tafel equation was utilized to determine the rate-determining step of the methoxylation process. A positive finding is that ILs stabilize intermediates and hinder an
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the Electrochemical Society
ISSN
0013-4651
e-ISSN
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Volume of the periodical
160
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
"G117"-"G123"
UT code for WoS article
000324810000099
EID of the result in the Scopus database
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