Nitrenic reactivity of diazirines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895609" target="_blank" >RIV/60461373:22310/13:43895609 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tetlet.2013.10.001" target="_blank" >http://dx.doi.org/10.1016/j.tetlet.2013.10.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tetlet.2013.10.001" target="_blank" >10.1016/j.tetlet.2013.10.001</a>
Alternative languages
Result language
angličtina
Original language name
Nitrenic reactivity of diazirines
Original language description
Butyl 3-bromo-3H-diazirine-3-carboxylate (7) and 3-bromo-3-phenyl-3H-diazirine exhibit nitrenic reactivity with phenylmagnesium bromide or tetrabutylammonium cyanide. The formation of several N,N?-disubstituted amidines is attributed to the intermediacyof 1-phenyl or 1-cyano-1H-diazirines possessing a singlet imidoylnitrene character at the N2 atom. Most notably, the reaction of 7 with PhMgBr in diethyl ether affords 2-hydroxy-2,2,N-triphenylacetamidine and 2-methyl-5,5-diphenyl-4-phenylamino-2,5-dihydrooxazole, products derived from nitrene insertion to the alpha-C?H bond of ether.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Tetrahedron Letters
ISSN
0040-4039
e-ISSN
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Volume of the periodical
54
Issue of the periodical within the volume
49
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
6764-6767
UT code for WoS article
000327285600023
EID of the result in the Scopus database
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