Thiophenium-ylides: synthesis and reactivity

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895695" target="_blank" >RIV/60461373:22310/13:43895695 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.2478/s11696-012-0222-7" target="_blank" >http://dx.doi.org/10.2478/s11696-012-0222-7</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.2478/s11696-012-0222-7" target="_blank" >10.2478/s11696-012-0222-7</a>

Result language
angličtina
Original language name
Thiophenium-ylides: synthesis and reactivity
Original language description
The reaction of propanedioic acid, 2-diazo-1,3-bis(1,1-dimethylethyl) ester (di-tert-butyl diazomalonate) with a series of cyclopenta[b]thiophenes in the presence of catalytic rhodium acetate was studied. The resulting S-C ylides underwent a rearrangement to form a heterocycle with different topology; thialene, in very low yields. Experimental and spectral data for all compounds are provided.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP204%2F11%2F0723" target="_blank" >GAP204/11/0723: Multifunctional self-assembling materials on nano-level</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Result description