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Thermodynamic properties of rock-salt ZnO

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895704" target="_blank" >RIV/60461373:22310/13:43895704 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.tca.2013.08.004" target="_blank" >http://dx.doi.org/10.1016/j.tca.2013.08.004</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.tca.2013.08.004" target="_blank" >10.1016/j.tca.2013.08.004</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermodynamic properties of rock-salt ZnO

  • Original language description

    Zinc oxide represents an important material with a wide variety of applications. At the temperature T=298.15 K and standard pressure p(o) = 100 kPa ZnO exists in the hexagonal wurtzite structure, which undergoes a transformation to rock salt polymorph under the pressure of approximate to 9 GPa. A consistent set of thermodynamic functions for ZnO in the high-pressure rock salt modification has been established on the basis of thorough evaluation of experimental and calculated data. Using literature datafor wurtzite ZnO, standard enthalpy of formation at 298.15 K for rock salt ZnO have been assessed as Delta H-f(o)(298.15 K)= -326.69 kJ mol(-1). Standard entropy S-m(o)(298.15 K)=45.42 J K-1 mol(-1) was derived from published low temperature heat capacity. The temperature dependence of the standard molar heat capacity above room temperature in the form C-pm(o) = 45.91 + 0.009089T - 604976/T-2 + 4.159 x 10(-6)T(2) (J K-1 mol(-1)) has been derived. The dataset is consistent with the transi

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Thermochimica Acta

  • ISSN

    0040-6031

  • e-ISSN

  • Volume of the periodical

    572

  • Issue of the periodical within the volume

    NOV 20 2013

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

    1-5

  • UT code for WoS article

    000327825100001

  • EID of the result in the Scopus database