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Nanosizing as a way to enhanced solubility of transition metals in ZnO

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43895708" target="_blank" >RIV/60461373:22310/13:43895708 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11051-013-1450-7" target="_blank" >http://dx.doi.org/10.1007/s11051-013-1450-7</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11051-013-1450-7" target="_blank" >10.1007/s11051-013-1450-7</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Nanosizing as a way to enhanced solubility of transition metals in ZnO

  • Original language description

    The solubility of nickel and cobalt oxides in ZnO nanoparticles was explored using the equilibrium thermodynamic approach. The equilibrium conditions were derived for the binary system ZnO-TMO (TM = Ni or Co) consists of two different spherical nanoparticles, one comprising the wurtzite (Zn1-xTMx)O(wz) solid solution and the second the rocksalt (TM1-xZnx)O(rs) solid solutions. Thermodynamic parameters for both phases were evaluated from bulk phase diagrams and the surface energy terms were included. Calculations of phase boundaries between the wurtzite and the rocksalt solid solutions reveal significant rise of the TM content in wurtzite phase. At the same time, the solubility of ZnO in rocksalt phase decreases. This behavior is more obvious for nanoparticles less than 5 nm in diameter and becomes more evident with increasing temperature. These results are in qualitative agreement with published experimental data.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Nanoparticle Research

  • ISSN

    1388-0764

  • e-ISSN

  • Volume of the periodical

    15

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    1450

  • UT code for WoS article

    000318551300005

  • EID of the result in the Scopus database