Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43898138" target="_blank" >RIV/60461373:22310/14:43898138 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om500182p" target="_blank" >http://dx.doi.org/10.1021/om500182p</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om500182p" target="_blank" >10.1021/om500182p</a>

Result language
angličtina
Original language name
Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
Original language description
Thiophene- and furan-derived aminocarbene complexes are regioselectively lithiated by BuLi at position 5, while lithiated aminocarbenes containing pyrrole or phenyl groups can be obtained by a bromine to lithium exchange reaction using BuLi. Such prepared lithiated aminocarbene complexes react with alkyl halides, aldehydes, ketones, acyl chlorides, and DMF, giving high yields of functionalized aminocarbene complexes hardly accessible by other ways.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/LC06070" target="_blank" >LC06070: The structure and synthetic applications of transition metal complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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