Definitive Insight into the Graphite Oxide Reduction Mechanism by Deuterium Labeling
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43899770" target="_blank" >RIV/60461373:22310/15:43899770 - isvavai.cz</a>
Alternative codes found
RIV/61389005:_____/15:00448982 RIV/44555601:13440/15:43886842
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500168/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500168/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.201500168" target="_blank" >10.1002/cplu.201500168</a>
Alternative languages
Result language
angličtina
Original language name
Definitive Insight into the Graphite Oxide Reduction Mechanism by Deuterium Labeling
Original language description
The reduction of graphite oxide is one of the most important reactions in the production of graphene in gram quantities. The mechanisms of these widely used reactions are poorly understood. The mechanism of the chemical reduction of two different graphite oxides prepared by the chlorate (Hofmann method) and permanganate methods (Hummers method) has been investigated. Three different reduction agents, lithium tetrahydridoaluminate, sodium tetrahydridoborate, and lithium tetrahydridoborate, as well as their deuterated counterparts, were used for the reduction of graphite oxide. Reduced graphite oxides were analyzed by scanning electron microscopy, energy-dispersive spectroscopy, elemental combustion analysis, Raman spectroscopy, high-resolution X-ray photoelectron spectroscopy, and simultaneous thermal analysis. The concentration of boron incorporated into graphene was measured by prompt gamma activation analysis. Rutherford back-scattering spectroscopy and elastic recoil detection analysis were used for the determination of the elemental composition, including deuterium concentration, as evidence of C-H bond formation.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
—
Volume of the periodical
80
Issue of the periodical within the volume
9
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
1399-1407
UT code for WoS article
000360825900005
EID of the result in the Scopus database
—