Thermodynamic model and structure of ZnO-MoO3-P2O5 glasses
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43899947" target="_blank" >RIV/60461373:22310/15:43899947 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10973-013-2988-4" target="_blank" >http://dx.doi.org/10.1007/s10973-013-2988-4</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-013-2988-4" target="_blank" >10.1007/s10973-013-2988-4</a>
Alternative languages
Result language
angličtina
Original language name
Thermodynamic model and structure of ZnO-MoO3-P2O5 glasses
Original language description
In the present work the Shakhmatkin & Vedishcheva thermodynamic model was constructed for the ZnO-MoO3-P2O5 glasses. On the basis of equilibrium phase diagrams and the crystal structural data the glass was considered as an ideal solution of three oxidesand nine compounds representing different Q(n) units. For the components considered in the model no thermodynamic data were available in contemporary thermodynamic databases. Therefore new method of parameterization of the thermodynamic model was proposed based on the known structural data. Four compositional series were considered. The first series (A) has equimolar content of ZnO/P2O5-(0.5-x/2)[ZnO.P2O5].xMoO(3). The other three series have a constant content of one of the components, (B) 0.1ZnO.yMoO(3).(0.9-y)P2O5, (C) zZnO.0.2MoO(3). (0.8-z)P2O5 and (D) (0.5-t)ZnO.tMoO(3).0.5P(2)O(5). For these compositional series the Q(n) distribution was obtained from the P-31 MAS NMR spectra by Subcik et al.((1)) Using these experimental data th
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
JH - Ceramics, fire-proof materials and glass
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GAP108%2F10%2F1631" target="_blank" >GAP108/10/1631: Modelling of vibration spectra of non-crystalline solids by molecular simulations</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physics and Chemistry of Glasses - European Journal of Glass Science and Technology Part B
ISSN
1753-3562
e-ISSN
—
Volume of the periodical
56
Issue of the periodical within the volume
2
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
63-66
UT code for WoS article
000354913200004
EID of the result in the Scopus database
—