Artificial flavin systems for chemoselective and stereoselective oxidations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43900595" target="_blank" >RIV/60461373:22310/15:43900595 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201403275/epdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201403275/epdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejoc.201403275" target="_blank" >10.1002/ejoc.201403275</a>

Result language
angličtina
Original language name
Artificial flavin systems for chemoselective and stereoselective oxidations
Original language description
Flavinium salts, both isoalloxazinium and alloxazinium derivatives, represent useful organocatalysts of redox reactions, and particularly in recent years, the number of transformations catalysed by flavinium salts has increased. This review delineates the synthetic applications of flavinium catalysts in oxygenation reactions with oxygen and hydrogen peroxide as terminal oxidising agents; these oxidations involve flavin hydroperoxide as an intermediate, thus mimicking flavin monooxygenases. Special attention is paid to mechanistic studies and to the design of catalytic systems especially to the effect of the structure of flavinium catalysts, and reaction conditions on the efficiency, chemoselectivity, and stereoselectivity of oxygenations.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)