H3PO3 electrochemical behaviour on a bulk Pt electrode: adsorption and oxidation kinetics
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F16%3A43901998" target="_blank" >RIV/60461373:22310/16:43901998 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.electacta.2016.07.045" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2016.07.045</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2016.07.045" target="_blank" >10.1016/j.electacta.2016.07.045</a>
Alternative languages
Result language
angličtina
Original language name
H3PO3 electrochemical behaviour on a bulk Pt electrode: adsorption and oxidation kinetics
Original language description
Polybenzimidazole-type polymer doped with H3PO4 is commonly used as the proton-conductive phase in high-temperature proton-exchange membrane fuel cells. However, H3PO4 is not stable during fuel cell operation and undergoes reduction by hydrogen on a Pt surface to phosphorus compounds in a lower oxidation state, such as H3PO3. In this work the kinetics of H3PO3 oxidation on Pt electrode was studied, including an investigation of H4P2O6 as a possible oxidation intermediate. H3PO3 adsorption in hydrogen underpotential deposition region was described by a triple Langmuir isotherm corresponding to adsorption on specific Pt crystalline planes. Co-adsorption of hydrogen as well as SO42MINUS SIGN , HSO4MINUS SIGN ions decreased the total amount of adsorbed H3PO3. The determined apparent charge transfer coefficients of H3PO3 anodic oxidation on a metallic Pt surface were found to be concentration and temperature-dependent, indicating that the nature of the anodic process is complex. From chronopotentiometric measurements of H3PO3 and H4P2O6 oxidation on a preoxidised Pt surface it was concluded that, while H3PO3 is oxidised by means of a chemical reaction with PtOx, H4P2O6 undegoes anodic oxidation on the PtOx surface. According to voltammetry and bulk electrolysis experiments H4P2O6 is not formed as an intermediate product during electrochemical oxidation of H3PO3 on a metallic Pt surface.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/7HX13002" target="_blank" >7HX13002: Understanding the Degradation Mechanisms of a High Temperature PEMFC Stack and Optimization of the Individual Components</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica Acta
ISSN
0013-4686
e-ISSN
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Volume of the periodical
212
Issue of the periodical within the volume
10 September 2016
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
"465?472"
UT code for WoS article
000382250200053
EID of the result in the Scopus database
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