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Pnictogen (As, Sb, Bi) Nanosheets for Electrochemical Applications Are Produced by Shear Exfoliation Using Kitchen Blenders

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913368" target="_blank" >RIV/60461373:22310/17:43913368 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22810/17:43913368

  • Result on the web

    <a href="http://onlinelibrary.wiley.com/doi/10.1002/anie.201706389/epdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/anie.201706389/epdf</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.201706389" target="_blank" >10.1002/anie.201706389</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Pnictogen (As, Sb, Bi) Nanosheets for Electrochemical Applications Are Produced by Shear Exfoliation Using Kitchen Blenders

  • Original language description

    Layered materials are of high importance because of their anisotropy and as a source of 2D materials. Whilst there is a plethora of multi-elemental 2D materials, the number mono-elemental 2D materials is rather limited. Herein, we demonstrate that aqueous shear exfoliation can be used to obtain As, Sb, and Bi exfoliated nanosheets. Morphological and chemical characterization of the exfoliated materials shows a decrease in thickness, sheet-to-nanosheet scale, and partial oxidation owing to a higher surface area. The electrochemical performance is tested in terms of inherent electrochemistry, electron transfer, and sensing applications as demonstrated with ascorbic acid. Potential energy-related applications are evaluated in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR), with shear-exfoliated Sb having the best electrochemical performance overall. These findings will have a profound impact on the preparation and application of 2D mono-elemental materials.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA15-09001S" target="_blank" >GA15-09001S: Chemical modifications of graphene based materials: Synthesis of graphane and halogengraphene</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Angewandte Chemie-International Edition

  • ISSN

    1433-7851

  • e-ISSN

  • Volume of the periodical

    56

  • Issue of the periodical within the volume

    46

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    14417-14422

  • UT code for WoS article

    000414764600010

  • EID of the result in the Scopus database

    2-s2.0-85032995892