The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913379" target="_blank" >RIV/60461373:22310/17:43913379 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/17:73584590 RIV/60461373:22810/17:43913379
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/ange.201705722/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/ange.201705722/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201705722" target="_blank" >10.1002/anie.201705722</a>
Alternative languages
Result language
angličtina
Original language name
The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents
Original language description
Layered black phosphorus has been attracting great attention due to its interesting material properties which lead to a plethora of proposed applications. Several approaches are demonstrated here for covalent chemical modifications of layered black phosphorus in order to form P-C and P-O-C bonds. Nucleophilic reagents are highly effective for chemical modification of black phosphorus. Further derivatization approaches investigated were based on radical reactions. These reagents are not as effective as nucleophilic reagents for the surface covalent modification of black phosphorus. The influence of covalent modification on the electronic structure of black phosphorus was investigated using ab initio calculations. Covalent modification exerts a strong effect on the electronic structure including the change of band-gap width and spin polarization.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie-International Edition
ISSN
1433-7851
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
33
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
9891-9896
UT code for WoS article
000406798700045
EID of the result in the Scopus database
2-s2.0-85024365279