Selective Bromination of Graphene Oxide by the Hunsdiecker Reaction

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913389" target="_blank" >RIV/60461373:22310/17:43913389 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/17:73584503

Result on the web

<a href="http://onlinelibrary.wiley.com/doi/10.1002/chem.201702031/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/chem.201702031/full</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/chem.201702031" target="_blank" >10.1002/chem.201702031</a>

Result language

angličtina

Original language name

Selective Bromination of Graphene Oxide by the Hunsdiecker Reaction

Original language description

Halogenated graphenes have been attracting great attention in the recent years. The currently used methods are usually non-specific, and halogen groups are randomly distributed over the graphene. Here we demonstrate a selective graphene functionalization based on a well known reaction mechanism?Hunsdiecker reaction?applied on selective bromination of graphene oxide. The chemical analysis using various spectroscopic methods proved a high efficiency of this functionalization method. Bromination can be carried out under mild conditions without any high temperature or high pressure treatment. The chemical modification led to introduction of up to 20 wt.% of bromine covalently bonded to the graphene skeleton. The modified graphene was characterized in detail using a broad range of microscopic and spectroscopic methods and no significant contamination by reaction by-products was detected.

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemistry A European Journal

ISSN

0947-6539

e-ISSN

—

Volume of the periodical

23

Issue of the periodical within the volume

43

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

10473-10479

UT code for WoS article

000406702100031

EID of the result in the Scopus database

2-s2.0-85022213338