Photocatalytic esterification under Mitsunobu reaction conditions mediated by flavin and visible light
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43914939" target="_blank" >RIV/60461373:22310/17:43914939 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22810/17:43914939
Result on the web
<a href="http://dx.doi.org/10.1039/c6ob02770a" target="_blank" >http://dx.doi.org/10.1039/c6ob02770a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c6ob02770a" target="_blank" >10.1039/c6ob02770a</a>
Alternative languages
Result language
angličtina
Original language name
Photocatalytic esterification under Mitsunobu reaction conditions mediated by flavin and visible light
Original language description
The usefulness of flavin-based aerial photooxidation in esterification under Mitsunobu reaction conditions was demonstrated, providing aerial dialkyl azodicarboxylate recycling/generation from the corresponding dialkyl hydrazine dicarboxylate. Simultaneously, activation of triphenylphosphine (Ph3P) by photoinduced electron transfer from flavin allows azo-reagent-free esterification. An optimized system with 3-methylriboflavin tetraacetate (10%), oxygen (terminal oxidant), visible light (450 nm), Ph3P, and dialkyl hydrazine dicarboxylate (10%) has been shown to provide efficient and stereoselective coupling of various alcohols and acids to esters with retention of configuration.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA16-09436S" target="_blank" >GA16-09436S: Photocatalytic and Organocatalytic Mitsunobu Reaction Mediated by Flavin derivatives and Visible Light</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organic and Biomolecular Chemistry
ISSN
1477-0520
e-ISSN
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Volume of the periodical
15
Issue of the periodical within the volume
9
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1969-1974
UT code for WoS article
000395928400006
EID of the result in the Scopus database
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