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Matrimid®5218 dense membrane for the separation of azeotropic MeOH-MTBE mixtures by pervaporation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43915953" target="_blank" >RIV/60461373:22310/18:43915953 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S1383586617338625?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1383586617338625?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.seppur.2018.01.045" target="_blank" >10.1016/j.seppur.2018.01.045</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Matrimid®5218 dense membrane for the separation of azeotropic MeOH-MTBE mixtures by pervaporation

  • Original language description

    Matrimid®5218 dense membranes were produced using NMP by solvent evaporation. The membranes have been used, for the first time, in pervaporation (PV) separation of azeotropic methanol (MeOH)- methyl tert-butyl ether (MTBE) mixtures (14.3 and 85.7 wt%, respectively). The membranes were characterized by TGA, SEM, DSC, contact angle and swelling tests. The PV experiments were carried out at different feed temperatures (25–45 °C) and vacuum pressures (0.0538, 0.2400, 2.1000 mbar). Moreover, an analysis of the PV process through the Arrhenius relationship has been provided. The feed temperature (in the range of 25–45 °C) affected mainly the MeOH permeation producing an increasing on its partial permeate flux and separation factor as well. Indeed, the best performances of Matrimid® were found at 45 °C and 0.054 mbar, where a permeate flux and a separation factor of about 0.073 kg m−2 h−1 and 21.16, respectively, were obtained. Finally, the Matrimid PV performance was compared with other polymeric membranes at the azeotropic conditions. © 2018 Elsevier B.V.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20401 - Chemical engineering (plants, products)

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Separation and Purification technology

  • ISSN

    1383-5866

  • e-ISSN

  • Volume of the periodical

    199

  • Issue of the periodical within the volume

    30 June 2018

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

    27-36

  • UT code for WoS article

    000430784500004

  • EID of the result in the Scopus database

    2-s2.0-85041423215