Template synthesis and structure of Co(II), Ni(II), and Cu(II) complexes with pyridoxilydenetaurinate Schiff base ligand
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43916272" target="_blank" >RIV/60461373:22310/18:43916272 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0020169317314226?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0020169317314226?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2018.03.031" target="_blank" >10.1016/j.ica.2018.03.031</a>
Alternative languages
Result language
angličtina
Original language name
Template synthesis and structure of Co(II), Ni(II), and Cu(II) complexes with pyridoxilydenetaurinate Schiff base ligand
Original language description
Co(II), Ni(II), and Cu(II) complexes with a Schiff base ligand pyridoxylidenetaurinate (L) were prepared by a template reaction of pyridoxal (3-hydroxy-5-(hydroxymethyl)-2-methylpyridine-4-carbaldehyde), taurine (2-aminoethane-1-sulfonic acid), and the corresponding metal acetate in water-ethanol solution. Composition of the product was [ML2(H2O)(2)] for all three central metals. Coordination geometry varied from weakly distorted octahedral (Co, Ni) to strongly distorted octahedral (Cu) with trans arrangement of both water molecules and imine N atoms. Each bidentate ligand formed one chelate ring via iminic N and phenolic O donor atoms. The complexes were characterised by elemental analysis, FTIR spectroscopy, and XRD crystal and powder analyses. All complexes crystallize in monoclinic system with space group P2(1)/c. IR spectra of the complexes showed changes typical for Schiff base coordination, comparing with IR spectrum of the ligand.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganica Chimica Acta
ISSN
0020-1693
e-ISSN
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Volume of the periodical
477
Issue of the periodical within the volume
May
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
248-256
UT code for WoS article
000429902200034
EID of the result in the Scopus database
2-s2.0-85044677550