Unexpected cleavage of upper rim-bridged calix[4]arenes leading to linear oligophenolic derivatives
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43916437" target="_blank" >RIV/60461373:22310/18:43916437 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22810/18:43916437
Result on the web
<a href="https://pubs.rsc.org/en/content/articlepdf/2018/ob/c7ob03101g" target="_blank" >https://pubs.rsc.org/en/content/articlepdf/2018/ob/c7ob03101g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c7ob03101g" target="_blank" >10.1039/c7ob03101g</a>
Alternative languages
Result language
angličtina
Original language name
Unexpected cleavage of upper rim-bridged calix[4]arenes leading to linear oligophenolic derivatives
Original language description
Regioselective meta-mercuration followed by Pd-catalysed intramolecular bridging gave birth to a novel type of calixarene bearing a single bond bridge between the meta positions of the neighboring aromatic subunits. These bridged derivatives possess extremely distorted cavities that imply possible amended properties over common calix[4]arenes. This new type of calixarene reactivity can be documented by acid-/electrophile-mediated cleavage of the basic macrocyclic skeleton leading to open oligomeric structures-the behavior of which has never been observed before in classic calix[4]arenes bearing alkoxy groups on the lower rim.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA16-13869S" target="_blank" >GA16-13869S: Intramolecularly bridged calixarenes as new building blocks in supramolecular chemistry</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organic and Biomolecular Chemistry
ISSN
1477-0520
e-ISSN
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Volume of the periodical
16
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
838-843
UT code for WoS article
000423787600022
EID of the result in the Scopus database
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