Reaction of lithiated thiophene-derived aminocarbene complexes with inorganic halides: Preparation of a heteroatom containing mono- and multicarbene complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43917260" target="_blank" >RIV/60461373:22310/19:43917260 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0022328X18309355" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0022328X18309355</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2018.12.015" target="_blank" >10.1016/j.jorganchem.2018.12.015</a>
Alternative languages
Result language
angličtina
Original language name
Reaction of lithiated thiophene-derived aminocarbene complexes with inorganic halides: Preparation of a heteroatom containing mono- and multicarbene complexes
Original language description
The reaction of lithiated pentacarbonyl [(N,N-dimethylamino) (2-thienyl)carbene]chromium (0) or pentacarbonyl [(N,N-dimethylamino) (2-thienyl)carbene]tungsten (0) with SOCl2, COCl2, Me3 SiCl, Me2SiCl2, Me3SnCl and SnCl4 afforded the corresponding carbene complexes, in which the chlorine was substituted with a 2-thienyl amino carbene moiety. Reaction with S2Cl2 afforded the corresponding biscarbene sulphide. In contrast, reactions with the phosphorous chlorides PCl3, POCl3, PhPCl2 and Ph2PCl were unsuccessful. The trimethylstannyl derivative was successfully used in Stille coupling with 4- nitroiodobenzene. The molecular structure of the tungsten tetracarbene derived from SnCl4 was obtained.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA17-21770S" target="_blank" >GA17-21770S: Modular Synthesis of New Fischer Biscarbene Complexes, their Structural Features and Synthetic Applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
882
Issue of the periodical within the volume
leden
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
90-95
UT code for WoS article
000456533700012
EID of the result in the Scopus database
2-s2.0-85059760881