Stereoselective synthesis of trisubstituted alkenyl Fischer aminocarbenes through self-mediated α-haloketone olefination
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43919925" target="_blank" >RIV/60461373:22310/19:43919925 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22810/19:43919925
Result on the web
<a href="https://reader.elsevier.com/reader/sd/pii/S0022328X19304140?token=F056B20F9F542E31C47FCA6DD2B03B0312CAE12954AAD25C7A0A60B76F538311D080A62DC3B66523DEF1B1C7452ECCD0" target="_blank" >https://reader.elsevier.com/reader/sd/pii/S0022328X19304140?token=F056B20F9F542E31C47FCA6DD2B03B0312CAE12954AAD25C7A0A60B76F538311D080A62DC3B66523DEF1B1C7452ECCD0</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2019.120971" target="_blank" >10.1016/j.jorganchem.2019.120971</a>
Alternative languages
Result language
angličtina
Original language name
Stereoselective synthesis of trisubstituted alkenyl Fischer aminocarbenes through self-mediated α-haloketone olefination
Original language description
The stereoselective synthesis of trisubstituted alkenes bearing Fischer aminocarbene moiety was developed. The structures of isolated complexes were determined by means of 2D NMR techniques and nOe. Disubstituted oxiranes were isolated as intermediates. Mechanism explaining observed reactivity was proposed based on experimental evidences.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA17-21770S" target="_blank" >GA17-21770S: Modular Synthesis of New Fischer Biscarbene Complexes, their Structural Features and Synthetic Applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
902
Issue of the periodical within the volume
902
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
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UT code for WoS article
000493061500014
EID of the result in the Scopus database
2-s2.0-85073498917