Oxidative addition of verdazyl halogenides to Pd(PPh3)4

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43934078" target="_blank" >RIV/60461373:22310/19:43934078 - isvavai.cz</a>
Result on the web
<a href="http://DOI" target="_blank" >http://DOI</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9nj03361k" target="_blank" >10.1039/c9nj03361k</a>

Result language
angličtina
Original language name
Oxidative addition of verdazyl halogenides to Pd(PPh3)4
Original language description
Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10400 - Chemical sciences

Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)