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Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43918137" target="_blank" >RIV/60461373:22310/20:43918137 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26620/20:PU136234

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.201902944" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.201902944</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/smll.201902944" target="_blank" >10.1002/smll.201902944</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Light-Driven ZnO Brush-Shaped Self-Propelled Micromachines for Nitroaromatic Explosives Decomposition

  • Original language description

    Self-propelled micromachines have recently attracted lots of attention for environmental remediation. Developing a large-scale but template-free fabrication of self-propelled rod/tubular micro/nanomotors is very crucial but still challenging. Here, a new strategy based on vertically aligned ZnO arrays is employed for the large-scale and template-free fabrication of self-propelled ZnO-based micromotors with H2O2-free light-driven propulsion ability. Brush-shaped ZnO-based micromotors with different diameters and lengths are fully studied, which present a fast response to multicycles UV light on/off switches with different interval times (2/5 s) in pure water and slow directional motion in aqueous hydrogen peroxide solution in the absence of UV light. Light-induced electrophoretic and self-diffusiophoretic effects are responsible for these two different self-motion behaviors under different conditions, respectively. In addition, the pH of the media and the presence of H2O2 show important effects on the motion behavior and microstructure of the ZnO-based micromotors. Finally, these novel ZnO-based brush-shaped micromotors are demonstrated in a proof-of-concept study on nitroaromatic explosive degradation, i.e., picric acid. This work opens a completely new avenue for the template-free fabrication of brush-shaped light-responsive micromotors on a large scale based on vertically aligned ZnO arrays.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA17-11456S" target="_blank" >GA17-11456S: Layered transition metal dichalcogenides nanostructures for electrocatalysis</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Small

  • ISSN

    1613-6810

  • e-ISSN

  • Volume of the periodical

    16

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

  • UT code for WoS article

    000484573000001

  • EID of the result in the Scopus database

    2-s2.0-85071331431