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Graphitic Carbon Nitride for Photocatalytic Air Treatment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920504" target="_blank" >RIV/60461373:22310/20:43920504 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27360/20:10245055 RIV/61989100:27710/20:10245055 RIV/60461373:22350/20:43920504

  • Result on the web

    <a href="https://www.mdpi.com/1996-1944/13/13/3038" target="_blank" >https://www.mdpi.com/1996-1944/13/13/3038</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/ma13133038" target="_blank" >10.3390/ma13133038</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Graphitic Carbon Nitride for Photocatalytic Air Treatment

  • Original language description

    Graphitic carbon nitride (g-C3N4) is a conjugated polymer, which recently drew a lot of attention as a metal-free and UV and visible light responsive photocatalyst in the field of solar energy conversion and environmental remediation. This is due to its appealing electronic band structure, high physicochemical stability and earth-abundant nature. In the present work, bulk g-C(3)N(4)was synthesized by thermal decomposition of melamine. This material was further exfoliated by thermal treatment. S-doped samples were prepared from thiourea or further treatment of exfoliated g-C(3)N(4)by mesylchloride. Synthesized materials were applied for photocatalytic removal of air pollutants (acetaldehyde and NOx) according to the ISO 22197 and ISO 22197-1 methodology. The efficiency of acetaldehyde removal under UV irradiation was negligible for all g-C(3)N(4)samples. This can be explained by the fact that g-C(3)N(4)under irradiation does not directly form hydroxyl radicals, which are the primary oxidation species in acetaldehyde oxidation. It was proved by electron paramagnetic resonance (EPR) spectroscopy that the dominant species formed on the irradiated surface of g-C(3)N(4)was the superoxide radical. Its production was responsible for a very high NO(x)removal efficiency not only under UV irradiation (which was comparable with that of TiO2), but also under visible irradiation.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA19-15199S" target="_blank" >GA19-15199S: Non-metal doped nanostructures of graphitic carbon nitride for photocatalytic reactions</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials

  • ISSN

    1996-1944

  • e-ISSN

  • Volume of the periodical

    13

  • Issue of the periodical within the volume

    13

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    14

  • Pages from-to

  • UT code for WoS article

    000550279400001

  • EID of the result in the Scopus database

    2-s2.0-85088038512