Regioselective SNAr reaction of the phenoxathiin based thiacalixarene as a route to a novel macrocyclic skeleton

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920953" target="_blank" >RIV/60461373:22310/20:43920953 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22810/20:43920953
Result on the web
<a href="https://pubs.rsc.org/en/content/articlehtml/2020/cc/c9cc08335a" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2020/cc/c9cc08335a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9cc08335a" target="_blank" >10.1039/c9cc08335a</a>

Result language
angličtina
Original language name
Regioselective SNAr reaction of the phenoxathiin based thiacalixarene as a route to a novel macrocyclic skeleton
Original language description
The sulfonyl analogue of phenoxathiin-based thiacalix[4]arene, easily accessible from the parent thiacalix[4]arene, reacts with sodium alkoxides to yield a cleaved product representing a novel type of macrocyclic skeleton with a quasi-calixarene structure. As shown by comparisonwith other derivatives, the internal strain imposed by the heterocyclic moiety is a driving force of this SNAr reaction.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA17-18108S" target="_blank" >GA17-18108S: Novel electrochemically active thiacalix[4]arenes and their oxidized analogues as ligands and receptors</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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