Electrochemical Exfoliation of Janus-like BiTeI Nanosheets for Electrocatalytic Nitrogen Reduction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43922111" target="_blank" >RIV/60461373:22310/21:43922111 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/abs/10.1021/acsanm.0c02860" target="_blank" >https://pubs.acs.org/doi/abs/10.1021/acsanm.0c02860</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsanm.0c02860" target="_blank" >10.1021/acsanm.0c02860</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical Exfoliation of Janus-like BiTeI Nanosheets for Electrocatalytic Nitrogen Reduction
Original language description
Bismuth nanosheets were recently shown to be excellent catalysts for the electrocatalytic nitrogen reduction reaction (NRR) to ammonia, and in addition, bismuth telluride iodide (BiTeI) has been labeled as a promising two-dimensional nanomaterial for energy applications, but it has been theoretically and experimentally investigated almost exclusively in its bulk state. Herein, we report for the first time the successful electrochemical exfoliation of BiTeI in DMF down to nanosheets of an average thickness of 10-20 nm without altering its hexagonal structure. The exfoliated nanosheets were evaluated for NRR, and they produced 1.04 ± 0.05 μg h-1 cm-2 of ammonia with a Faradaic efficiency of 1.67 ± 0.10% at -0.5 V vs Ag/AgCl in 0.1 M KOH. © 2020 American Chemical Society.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GC20-16124J" target="_blank" >GC20-16124J: Two-dimensional layered transition metal dichalcogenides/ nanostructured carbons composites for electrochemical energy storage and conversion</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Applied Nano Materials
ISSN
2574-0970
e-ISSN
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Volume of the periodical
4
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
590-599
UT code for WoS article
000613246600065
EID of the result in the Scopus database
2-s2.0-85099858452