Cobalt Phosphorous Trisulfide as a High-Performance Electrocatalyst for the Oxygen Evolution Reaction

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43922148" target="_blank" >RIV/60461373:22310/21:43922148 - isvavai.cz</a>

Result on the web

<a href="https://pubs.acs.org/doi/full/10.1021/acsami.1c02361" target="_blank" >https://pubs.acs.org/doi/full/10.1021/acsami.1c02361</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsami.1c02361" target="_blank" >10.1021/acsami.1c02361</a>

Result language

angličtina

Original language name

Cobalt Phosphorous Trisulfide as a High-Performance Electrocatalyst for the Oxygen Evolution Reaction

Original language description

Two-dimensional (2D) layered materials are currently one of the most explored materials for developing efficient and stable electrocatalysts in energy conversion applications. Some of the 2D metal phosphorous trichalcogenides (M2P2X6 or MPX3 in its simplified form) have been reported to be useful catalysts for water splitting, although results have been less promising for the sluggish oxygen evolution reaction (OER) due to insufficient activity or compromised stability. Herein, we report the OER catalysis of a series of M2P2X6 (M2+ = Mn, Fe, Co, Zn, Cd; X = S, Se). From the series of MPX3, CoPS3 yields the best results with an overpotential within the range of values usually obtained for IrO2 or RuO2 catalysts. The liquid-phase exfoliation of CoPS3 even improves the OER activity due to abundant active edges of the downsized sheets, accompanied by the presence of surface oxides. The influence of the OER medium and underlying substrate electrode is studied, with the exfoliated CoPS3 reaching the lowest overpotential at 234 mV at a current density of 10 mA/cm2, also able to sustain high current densities, with an overpotential of 388 mV at a current density of 100 mA/cm2, and excellent stability after multiple cycles or long-term operation. Quantum chemical models reveal that these observations are likely tied to moieties on CoPS3 edges, which are responsible for low overpotentials through a two-site mechanism. The OER performance of exfoliated CoPS3 reported herein yields competitive values compared to those reported for other Co-based and MPX3 in the literature, thus holding substantial promise for use as an efficient material for the anodic water-splitting reaction. © 2021 American Chemical Society.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

<a href="/en/project/GJ20-21523Y" target="_blank" >GJ20-21523Y: 2D Layered Metal Phosphorous Trichalcogenides for Energy Conversion and Storage</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ACS Applied Materials and Interfaces

ISSN

1944-8244

e-ISSN

—

Volume of the periodical

13

Issue of the periodical within the volume

20

Country of publishing house

US - UNITED STATES

Number of pages

9

Pages from-to

23638-23646

UT code for WoS article

000657202500029

EID of the result in the Scopus database

2-s2.0-85106371694