Mineralizer-free synthesis of orthorhombic arsenic-phosphorus alloys
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43922172" target="_blank" >RIV/60461373:22310/21:43922172 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S2452262721000763" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2452262721000763</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.flatc.2021.100297" target="_blank" >10.1016/j.flatc.2021.100297</a>
Alternative languages
Result language
angličtina
Original language name
Mineralizer-free synthesis of orthorhombic arsenic-phosphorus alloys
Original language description
Phosphorus and arsenic belong to the same group of periodic table and especially the former is very intensively studied. Despite this, under normal conditions, phosphorus has an orthorhombic structure whereas arsenic is rhombohedral. Research concerning the orthorhombic allotrope of arsenic is very scarce due to its limited availability and in addition, As-P alloys have been predicted to possess unique features. In this manuscript, we studied the formation of As-P alloys using condensation of vapor in various As-P ratio in the range of 50 to 100 at. % of arsenic. We observed the formation of orthorhombic arsenic in the range of 50 to 70 at.% of arsenic, While for 80 at.% and 90 at.% the rhombohedral structure of arsenic remained unchanged. The formation of orthorhombic true van der Waals As-P alloys was obtained without addition of any mineralizers such as copper or tin iodides providing high purity material.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/LL2003" target="_blank" >LL2003: Next Generation of 2D Monoelemental Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
FlatChem
ISSN
2452-2627
e-ISSN
—
Volume of the periodical
30
Issue of the periodical within the volume
November 2021
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
—
UT code for WoS article
000714748000004
EID of the result in the Scopus database
—