Electrochemical investigation of structurally varied azinium scaffolds
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43923492" target="_blank" >RIV/60461373:22310/21:43923492 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/21:39917654 RIV/60461373:22340/21:43923492
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/OB/D1OB01758F" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/OB/D1OB01758F</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1ob01758f" target="_blank" >10.1039/d1ob01758f</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical investigation of structurally varied azinium scaffolds
Original language description
Inspired by the successful utilization of aziniums as anolytes in redox-flow batteries, we have designed and prepared a systematically extended series of (di)azinium compounds based on pyrazine, bipyridine, 1,5-naphthyridine, 3,8-phenanthroline, (E)-4,4′-diazastilbene and 1,2-bis(pyridin-4-yl)acetylene. It has been revealed that the fundamental electrochemical properties are affected mostly by the water-solubility and chemical stability of the particular redox forms. Based on the systematically evolved azinium structure and gathered electrochemical data, structure-property relationships were thoroughly elucidated. Further investigation on flow battery cells identified that the known 4,4′-bipyridinium decorated with two peripheralN-propyl-3-sulfonato pendants allows utilizing both redox steps with good cycling stability, while the naphthyridine scaffold turned out to be a new and promising scaffold for redox-flow batteries. © The Royal Society of Chemistry 2021.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20402 - Chemical process engineering
Result continuities
Project
<a href="/en/project/EF16_025%2F0007445" target="_blank" >EF16_025/0007445: Organic redox couple based batteries for energetics of traditional and renewable resources.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>O - Projekt operacniho programu
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organic and Biomolecular Chemistry
ISSN
1477-0520
e-ISSN
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Volume of the periodical
19
Issue of the periodical within the volume
40
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
8830-8839
UT code for WoS article
000698431900001
EID of the result in the Scopus database
2-s2.0-85117298636