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Physical Properties and Biodegradability Evaluation of Vulcanized Epoxidized Natural Rubber/Thermoplastic Potato Starch Blends

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F22%3A43924034" target="_blank" >RIV/60461373:22310/22:43924034 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.mdpi.com/1996-1944/15/21/7478" target="_blank" >https://www.mdpi.com/1996-1944/15/21/7478</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/ma15217478" target="_blank" >10.3390/ma15217478</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Physical Properties and Biodegradability Evaluation of Vulcanized Epoxidized Natural Rubber/Thermoplastic Potato Starch Blends

  • Original language description

    The sustainable material—thermoplastic potato starch (TPS)—was blended with modified natural rubber–epoxidized natural rubber (ENR). The poor mechanical properties of the ENR/TPS blends limited the application. Sulfur vulcanization is a common and economical method to improve the mechanical properties in the rubber industry. To fully understand the relationship between vulcanization systems and ENR/TPS blends and the sustainability of the developed material, the effects of a vulcanization accelerator (N-cyclohexylbenzothiazole-2-sulphenamide (CBS), 2-mercaptobenzothiazole (MBT), N-tert-butylbenzothiazole-2-sulphenamide (TBBS)) and a system type (conventional vulcanization (CV), semi-efficient vulcanization (SEV) and efficient vulcanization (EV)) on curing characteristics, mechanical and thermal properties, water absorption and biodegradability were systematically evaluated. The results indicate that vulcanization significantly improves the mechanical properties of ENR/TPS blends. The performance optimization of the CBS-CV vulcanization system is the best for improving the mechanical properties and reducing the water absorption. The CBS-CV curing system makes ENR/TPS less biodegradable (12–56% of mass loss) than other accelerators and systems. TBBS-CV makes the material more biodegradable (18–66% of mass loss). The low rubber content enables the rapid biodegradation of the vulcanized blend. This has implications for research on sustainable materials. The material can be applied for eco-friendly packaging and agricultural films, etc. The investigation on performance by using common accelerators and systems provides ideas for industries and research.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials

  • ISSN

    1996-1944

  • e-ISSN

    1996-1944

  • Volume of the periodical

    15

  • Issue of the periodical within the volume

    21

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    16

  • Pages from-to

    7478

  • UT code for WoS article

    000881182200001

  • EID of the result in the Scopus database

    2-s2.0-85141820182