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Powering the Future: Unleashing the Potential of MXene-Based Dual-Functional Photoactive Cathodes in Photo-Rechargeable Zinc-Ion Capacitor

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43927421" target="_blank" >RIV/60461373:22310/23:43927421 - isvavai.cz</a>

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202305972" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202305972</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/smll.202305972" target="_blank" >10.1002/smll.202305972</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Powering the Future: Unleashing the Potential of MXene-Based Dual-Functional Photoactive Cathodes in Photo-Rechargeable Zinc-Ion Capacitor

  • Original language description

    Dual-functional photo-rechargeable (photo-R) energy storage devices, which acquire stored energy from solar energy harvesting, are being developed to battle the current energy crisis. In this study, these findings on the photo-driven characteristics of MXene-based photocathodes in photo-R zinc-ion capacitors (ZICs) are presented. Along with the pristine Ti3C2Tx MXene, tellurium/Ti3C2Tx (Te/Ti3C2Tx) hybrid nanostructure is synthesized via facile chemical vapor transport technique to examine them for photocathodes in ZICs. Interestingly, the evaluated self-powered photodetector devices using MXene-based samples revealed a pyro-phototronic behavior introduced into the samples, with higher desirability observed in Te/Ti3C2Tx. The photo-R ZICs results exhibited a capacitance enhancement of 50.86% for Te/Ti3C2Tx at two scan rates of 5 and 10 mV s−1 under illumination, compared to dark conditions. In contrast, a capacitance enhancement of 30.20% is obtained for the pristine Ti3C2Tx at only a 5 mV s−1 scan rate. Furthermore, both samples achieved photo-charging voltage responses of ≈960 mV, and photoconversion efficiencies of 0.01% (for Te/ Ti3C2Tx) and 0.07% (for Ti3C2Tx). These characteristics in MXene-based single photo-R ZICs are significant and considerable with the distinguished integrated photo-R supercapacitors with solar cells, or coupled energy-harvesting and energy-storing devices reported recently in the literature.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    <a href="/en/project/LL2101" target="_blank" >LL2101: Next Generation of 2D Monoelemental Materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Small

  • ISSN

    1613-6810

  • e-ISSN

    1613-6829

  • Volume of the periodical

    neuveden

  • Issue of the periodical within the volume

    OCT 2023

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    14

  • Pages from-to

  • UT code for WoS article

    001090481600001

  • EID of the result in the Scopus database

    2-s2.0-85174681720