High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43933964" target="_blank" >RIV/60461373:22310/23:43933964 - isvavai.cz</a>
Result on the web
<a href="https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202214078" target="_blank" >https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202214078</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adfm.202214078" target="_blank" >10.1002/adfm.202214078</a>
Alternative languages
Result language
angličtina
Original language name
High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal
Original language description
3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (approximate to 124 AW(-1) at 405 nm) that is approximate to 4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)(2)PbBr4 and (PEA)(2)PbBr4, and large specific detectivity (approximate to 10(12) Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (approximate to 6.5 mu J cm(-2)) with angular dependent narrow linewidth (approximate to 0.1 nm) and high-quality factor (Q approximate to 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ADVANCED FUNCTIONAL MATERIALS
ISSN
1616-301X
e-ISSN
1616-3028
Volume of the periodical
33
Issue of the periodical within the volume
17
Country of publishing house
DE - GERMANY
Number of pages
10
Pages from-to
2214078
UT code for WoS article
000928813000001
EID of the result in the Scopus database
2-s2.0-85147504234