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Thermodynamic properties of the phosphate glass Dy(PO3)3 – Potential influence of boson peak on spin relaxation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43934013" target="_blank" >RIV/60461373:22310/23:43934013 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216275:25310/23:39920491

  • Result on the web

    <a href="https://doi.org/10.1016/j.jmmm.2023.171415" target="_blank" >https://doi.org/10.1016/j.jmmm.2023.171415</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jmmm.2023.171415" target="_blank" >10.1016/j.jmmm.2023.171415</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermodynamic properties of the phosphate glass Dy(PO3)3 – Potential influence of boson peak on spin relaxation

  • Original language description

    An experimental study was conducted to investigate the magnetic properties of dysprosium-doped phosphate glasses. Low-temperature (LT) measurements of the specific heat of Dy(PO3)3 were performed in the range of 0.38–300 K in the magnetic fields up to 9 T. The LT specific heat of amorphous materials is characterized by the presence of a broad maximum named boson peak (BP). The LT specific heat of the Dy-doped sample is dominated by the magnetic contribution, which overlaps the BP. Due to that reason, the specific heat of Y(PO3)3 nonmagnetic glasses was also measured at the same temperature range, revealing the BP at 12–14 K. The magnetic susceptibility was measured from 1.8 K up to room temperature, yielding the effective magnetic moment of 10.65 μB, which is close to the theoretical prediction for Dy3+. Magnetization curves were measured up to B = 5 T with temperatures ranging from 2 to 50 K. X-band electron-paramagnetic resonance spectra were measured from 0 to 1 T, revealing a maximum at 100 mT. The line achieves maximal intensity at temperatures around 12–14 K, which coincides with the appearance of BP in specific heat. The coincidence suggests the presence of the magnetoelastic coupling between the ground quasi-doublet and boson peak. © 2023

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/GA21-02550S" target="_blank" >GA21-02550S: Plasmon induced excited spin state trapping in spin-crossover complexes</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS

  • ISSN

    0304-8853

  • e-ISSN

  • Volume of the periodical

    588

  • Issue of the periodical within the volume

    DEC 15 2023

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

    "171415/1"-5

  • UT code for WoS article

    001108690900001

  • EID of the result in the Scopus database

    2-s2.0-85175457101