Reciprocating thermal behavior in a magnetic field induced slow spin relaxation of [Gd2(H2O)6(C2O4)3]∙2.5H2O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43934029" target="_blank" >RIV/60461373:22310/23:43934029 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.solidstatesciences.2022.107105" target="_blank" >https://doi.org/10.1016/j.solidstatesciences.2022.107105</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.solidstatesciences.2022.107105" target="_blank" >10.1016/j.solidstatesciences.2022.107105</a>
Alternative languages
Result language
angličtina
Original language name
Reciprocating thermal behavior in a magnetic field induced slow spin relaxation of [Gd2(H2O)6(C2O4)3]∙2.5H2O
Original language description
Static and alternating magnetic susceptibility, magnetization, and electron-spin resonance studies of Gd(III) complex [Gd2(H2O)6(C2O4)3]∙2.5H2O enabled its identification as an S = 7/2 magnet with easy-axis anisotropy D/kB = −91.2 mK and magnetic interaction effectively mediated by dipolar coupling │J/kB│ ≈ 12 mK. The magnetic field–induced slow relaxation at high temperatures is ascribed to direct relaxation with a pronounced effect of phonon bottleneck and Raman process. In contrast, relaxation at low temperatures displays reciprocating thermal behavior, where spin dynamics accelerates upon cooling. The potential origin of the observed behavior is discussed. © 2022 Elsevier Masson SAS
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA20-01768S" target="_blank" >GA20-01768S: Smart magnetic materials: from bulk systems towards “spinterface”</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
SOLID STATE SCIENCES
ISSN
1293-2558
e-ISSN
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Volume of the periodical
136
Issue of the periodical within the volume
FEB 2023
Country of publishing house
FR - FRANCE
Number of pages
9
Pages from-to
"107105/1"-9
UT code for WoS article
000916224200001
EID of the result in the Scopus database
2-s2.0-85145662646